THE STRUCTURE OF GLASSES STUDIED BY MAS-NMR SPECTROSCOPY OF QUADRUPOLAR NUCLEI

Authors
MULLERWARMUTH W
Citation
W. Mullerwarmuth, THE STRUCTURE OF GLASSES STUDIED BY MAS-NMR SPECTROSCOPY OF QUADRUPOLAR NUCLEI, Zeitschrift fur Naturforschung. A, A journal of physical sciences, 51(5-6), 1996, pp. 585-590
Citations number
21
Categorie Soggetti
Chemistry Physical",Physics
Journal title
Zeitschrift fur Naturforschung. A, A journal of physical sciences → ACNP
ISSN journal
09320784
Volume
51
Issue
5-6
Year of publication
1996
Pages
585 - 590
Database
ISI
SICI code
0932-0784(1996)51:5-6<585:TSOGSB>2.0.ZU;2-5
Abstract
High-resolution solid state NMR spectroscopy of quadrupolar nuclei (pr eferentially B-11 and Al-27) has been employed to study the microstruc ture of glasses. Importance has been attached to the extraction of the fundamental NMR parameters like chemical shift, quadrupole coupling c onstant etc., from the spectra, first of all by applying satellite tra nsition spectroscopy. Exemplary results are represented for ternary ox ide glass systems such as K2O-Al2O3-SiO2, B2O3-Al2O3-P2O5, Na2O-B2O3-S iO2 and Na2O-B2O3-Al2O3.