Ai. Kharkovskii et al., MAGNETIC-PROPERTIES OF THE BISMUTH OXIDE ALPHA-BI2O3, Zeitschrift fur Naturforschung. A, A journal of physical sciences, 51(5-6), 1996, pp. 665-666
A very unusual magnetic behaviour of alpha - Bi2O3 was observed in a w
ide range of temperatures and magnetic fields. A longitudinal magnetoe
lectric effect was found at 4.2 K. The existence of an antiferroelectr
ically ordered subsystem of electric dipoles in alpha - Bi2O3 is propo
sed. The mechanism of spin-orbit coupling is regarded as the physical
origin for the occurrence of the ordered magnetic moments in alpha - B
i2O3.