This work studies the effects of T. reesei xylanase and mannanase trea
tments on the bleaching of radiata pine and northern pine sulfate pulp
s in three-stage peroxide- and chlorine dioxide-based DED bleaching se
quences. The xylanase treatment was more effective in enhancing pulp b
leaching than the mannanase treatment. Pulp origin, method of pulping,
and the sequence used in bleaching influenced the effectiveness of en
zymatic treatment. Enzymatic treatment affected bleaching of northern
pine kraft pulp more than radiata pine kraft with a similar kappa numb
er. Radiata pine kraft pulp responded more readily to the xylanase and
less readily to the mannanase treatment than the radiata pine modifie
d continuous cooking pulp. Application:Progress toward more environmen
tally friendly bleaching sequences has created a need for easily bleac
hed kraft pulps. This work suggests that using a suitable combination
of enzyme treatment and bleaching sequence can enhance the bleachabili
ty of low kappa number pulps produced by modified or new kraft pulping
methods.