Nj. Fortey et al., SILURIAN AND LATE ORDOVICIAN K-BENTONITES AS A RECORD OF LATE CALEDONIAN VOLCANISM IN THE BRITISH-ISLES, Transactions of the Royal Society of Edinburgh. Earth sciences, 86, 1996, pp. 167-180
Silurian and late Ordovician K-bentonites of the British Isles provide
a record of prolonged volcanism during the convergence of terranes as
sociated with closure of the Iapetus and Tornquist Oceans. In the Sout
hern Uplands-Longford-Down and Midland Valley terranes, they range fro
m late Caradoc to Telychian, with further early Homerian occurrences.
South of the Iapetus suture, in Eastern Avalonia, the range is Hirnant
ian to early Ludlow in northern England and early Telychian to earlies
t Ludfordian in the Welsh Borderland and English Midlands. In both cas
es, the distributions indicate that volcanism was more long-lived and
probably more extensive than is depicted in current plate tectonic rec
onstructions. Average intervals between K-bentonites are estimated, ba
sed on Harland er al. (1990), as: c. 65 000 years at Dob's Linn (late
Aeronian to early Telychian); c. 39 000 years in the Cautley area (Tel
ychian); c. 51 000 years in a borehole at Walsall (late Llandovery to
Sheinwoodian). Trace element geochemistry suggests mostly subalkaline
dacitic to rhyolitic magmas in which LILE-enrichment accompanies varia
ble enrichment in crustally derived elements (Ta, Nb). The geochemistr
y suggests comparison with continental are volcanism of 'within-plate,
attenuated lithosphere' character. Ta-Nb enrichment and an absence of
Eu anomalies from REE profiles are consistently present north of the
Iapetus suture, but trace element patterns are less consistent south o
f the suture where negative Eu anomalies are generally present. Discri
minant function analysis successfully distinguishes Llandovery, Wenloc
k and Ludlow K-bentonites from south of the Iapetus suture, and Llando
very K-bentonites from north and south of the suture. Those from north
of the Iapetus suture probably originated in volcanism along the sout
hern margin of Laurentia before final closure of the Iapetus Ocean. Th
ose from south of the suture may have been derived from volcanism asso
ciated with late destruction of Iapetus and Tornquist oceanic crust, a
lthough an alternative involving volcanism at the southern margin of E
astern Avalonia or Baltica may accord better with the distribution of
K-bentonites and the geographical trend of the fragmentary outcrops of
Silurian volcanic rocks from southern Ireland to Belgium.