SYNTHESIS AND CHARACTERIZATION OF ZINC(II) OXYDIACETATE (ODA) COMPLEXES - CRYSTAL-STRUCTURES OF [(ZN(ODA)CENTER-DOT-0.3H(2)O)(N)], [ZN(ODA)(BIPY)(H2O)]CENTER-DOT-2.5H(2)O AND [ZN(ODA)(PHEN)(H2O)]CENTER-DOT-1.5H(2)O (BIPY=2,2'-BIPYRIDINE, PHEN=1,10-PHENANTHROLINE)

Authors
BAGGIO R GARLAND MT PEREC M
Citation
R. Baggio et al., SYNTHESIS AND CHARACTERIZATION OF ZINC(II) OXYDIACETATE (ODA) COMPLEXES - CRYSTAL-STRUCTURES OF [(ZN(ODA)CENTER-DOT-0.3H(2)O)(N)], [ZN(ODA)(BIPY)(H2O)]CENTER-DOT-2.5H(2)O AND [ZN(ODA)(PHEN)(H2O)]CENTER-DOT-1.5H(2)O (BIPY=2,2'-BIPYRIDINE, PHEN=1,10-PHENANTHROLINE), Journal of the Chemical Society. Dalton transactions, (13), 1996, pp. 2747-2753
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
13
Year of publication
1996
Pages
2747 - 2753
Database
ISI
SICI code
0300-9246(1996):13<2747:SACOZO>2.0.ZU;2-V
Abstract
Three novel zinc(II) oxydiacetate (oda) compounds [{Zn(oda). 0.3H(2)O} (n)] 1, [Zn(oda)(bipy)(H2O)]. 2.5H(2)O 2 (bipy = 2,2'-bipyridine) and [Zn(oda)(phen)(H2O)]. 1.5H(2)O 3 (phen = 1,10-phenanthroline) have bee n synthesized and their structures determined by single-crystal X-ray diffraction methods. Compound 1 consists of polymeric sheets formed by ZnO5 units bridged by carboxylate groups in anti-syn conformation alo ng the z axis; 2 and 3 are mononuclear with the zinc atoms in distorte d octahedral ZnN2O4 co-ordination geometries. Thermal decomposition of the compounds under an oxygen atmosphere affords ZnO at ca. 500 degre es C.