SYNTHESES OF SOME BETA-SUBSTITUTED ALKYNE PORPHYRINS RELATED TO PROTOPORPHYRIN-IX

Authors
JIANG XQ SMITH KM
Citation
Xq. Jiang et Km. Smith, SYNTHESES OF SOME BETA-SUBSTITUTED ALKYNE PORPHYRINS RELATED TO PROTOPORPHYRIN-IX, Journal of the Chemical Society. Perkin transactions. I, (13), 1996, pp. 1601-1606
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
13
Year of publication
1996
Pages
1601 - 1606
Database
ISI
SICI code
0300-922X(1996):13<1601:SOSBAP>2.0.ZU;2-Z
Abstract
beta-Acetylporphyrins (e.g. 20, 35, 39) have been treated with Vilsmei er complex (POCl3-DMF) to afford beta-(1-chloro-2-formylvinyl)porphyri ns (23, 36, 41); with an excess of KOH in methanol these compounds wer e transformed into the corresponding alkynylporphyrins (17, 37, 38). T he bis-alkynyl-porphyrin 17 was transformed into the corresponding hem in 25 by treatment with iron(II) chloride.