VERSATILE 3-SYNTHESES OF ACENAPHTHOPORPHYRINS, A NEW FAMILY OF HIGHLYCONJUGATED TETRAPYRROLES(1)

Authors
CHANDRASEKAR P LASH TD
Citation
P. Chandrasekar et Td. Lash, VERSATILE 3-SYNTHESES OF ACENAPHTHOPORPHYRINS, A NEW FAMILY OF HIGHLYCONJUGATED TETRAPYRROLES(1), Tetrahedron letters, 37(28), 1996, pp. 4873-4876
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
28
Year of publication
1996
Pages
4873 - 4876
Database
ISI
SICI code
0040-4039(1996)37:28<4873:V3OAAN>2.0.ZU;2-B
Abstract
Acenaphthoporphyrins, a new group of porphyrins with strongly red shif ted electronic absorption spectra, have been prepared by the acid cata lysed condensation of a pyrrole-2,5-dicarboxaldehyde with acenaphthotr ipyrranes: similarly, c-annelated pyrroledialdehydes afforded the rela ted opp-diacenaphthoporphyrins and a mixed porphyrin system with fused phenanthrene and acenaphthylene rings. Copyright (C) 1996 Elsevier Sc ience Ltd