Multicharged Xe-q+-ions (q < 20) are scattered with keV energies under
a grazing angle of incidence from the surface of two different insula
tors: LiF(100) and KI(100). From the analysis of angular distributions
for scattered projectiles we deduce energy gains caused by the dielec
tric response of the target material due to the presence of the extern
al charge (''image charge interaction''). A direct comparison of the i
nteraction energies gained by the projectiles on the incident path wit
h the two different targets is consistent with the assumption of a dom
inant population of Rydberg levels (''hollow atom'') in front of insul
ators for grazing ion-surface scattering.