P. Marzal et al., CADMIUM AND ZINC ADSORPTION ONTO ACTIVATED CARBON - INFLUENCE OF TEMPERATURE, PH AND METAL CARBON RATIO/, Journal of chemical technology and biotechnology, 66(3), 1996, pp. 279-285
The adsorption characteristics of cadmium and zinc onto a granular act
ivated carbon were studied. Cadmium and zinc removals increased on rai
sing pH and temperature, and decreased on raising the molar metal/carb
on ratio. The adsorption processes were modelled using the surface com
plex formation (SCF) Triple Layer Model (TLM) with an overall bidentat
e species. A dependence of the SCF constant on pH, the molar metal/car
bon ratio and temperature was observed, and a correlation for log K-ad
s was determined. The SCF model successfully predicted cadmium and zin
c removals.