CARBONYLMETALLATES AND CARBANIONS IN AROMATIC AND VINYLIC NUCLEOPHILIC-SUBSTITUTION

Authors
BELETSKAYA IP ARTAMKINA GA MILCHENKO AY SAZONOV PK SHTERN MM
Citation
Ip. Beletskaya et al., CARBONYLMETALLATES AND CARBANIONS IN AROMATIC AND VINYLIC NUCLEOPHILIC-SUBSTITUTION, Journal of physical organic chemistry, 9(6), 1996, pp. 319-328
Citations number
47
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Journal of physical organic chemistry → ACNP
ISSN journal
08943230
Volume
9
Issue
6
Year of publication
1996
Pages
319 - 328
Database
ISI
SICI code
0894-3230(1996)9:6<319:CACIAA>2.0.ZU;2-F
Abstract
The kinetic data on the reactions of carbonylmetallates M'M(CO)(n)L(m) , with polyfluorinated arenes and alkenes are reported. The behaviour of these transition metal anionic nucleophiles is compared with the re activity of both carbanions, and non-transition metal centred anions.