FRAGMENTATION OF AN IMIDO TIN(II) CUBANE - SYNTHESES AND STRUCTURES OF HETEROBIMETALLIC COMPLEXES CONTAINING TIN(II) IMIDO AND PHOSPHINIDINE ANIONS

Authors
ALLAN RE BESWICK MA CROMHOUT NL PAVER MA RAITHBY PR STEINER A TREVITHICK M WRIGHT DS
Citation
Re. Allan et al., FRAGMENTATION OF AN IMIDO TIN(II) CUBANE - SYNTHESES AND STRUCTURES OF HETEROBIMETALLIC COMPLEXES CONTAINING TIN(II) IMIDO AND PHOSPHINIDINE ANIONS, Chemical communications, (13), 1996, pp. 1501-1502
Citations number
30
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
13
Year of publication
1996
Pages
1501 - 1502
Database
ISI
SICI code
1359-7345(1996):13<1501:FOAITC>2.0.ZU;2-N
Abstract
The reactions of the imido tin(II) cubane [SnNBu(t)](4) with 3 equiv. of [C10H7NHLi] (C10H7 = 1-naphthyl) and 6 equiv. of [C6H11PHLi] (C6H11 = cyclohexyl) produce [Li(thf)(4)](+)[(Bu(t)N)(C10H7N)(3)Sn3Li . thf] (-). thf . PhMe 1 and [{Sn-2(PC6H11)(3)}Li-2(4) . 4thf]. 2thf 2, respe ctively, containing the first structurally characterised polyimido and polyphosphinidine anions of a divalent group 14 metal.