A STRONG ANTIFERROMAGNETIC INTERACTION BETWEEN IMINO NITROXIDES THROUGH A PD-II ION

Authors
OSHIO H OHTO A ITO T
Citation
H. Oshio et al., A STRONG ANTIFERROMAGNETIC INTERACTION BETWEEN IMINO NITROXIDES THROUGH A PD-II ION, Chemical communications, (13), 1996, pp. 1541-1542
Citations number
14
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
13
Year of publication
1996
Pages
1541 - 1542
Database
ISI
SICI code
1359-7345(1996):13<1541:ASAIBI>2.0.ZU;2-4
Abstract
A palladium(II) complex with imino nitroxides, [PdCl2(immepy)(2)] [imm epy = ,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxy], shows a stron g antiferromagnetic interaction between the coordinated imino nitroxid es, which results from indirect overlap of radical SOMOs through a d(x y) orbital.