POLYACETYL-SUBSTITUTED TETRATHIAFULVALENES AND 1,3-DITHIOLIC DERIVATIVES FROM HEX-3-YN-2,5-DIONE

Authors
LERICHE P BELYASMINE A SALLE M FRERE P GORGUES A RION A JUBAULT M ORDUNA J GARIN J
Citation
P. Leriche et al., POLYACETYL-SUBSTITUTED TETRATHIAFULVALENES AND 1,3-DITHIOLIC DERIVATIVES FROM HEX-3-YN-2,5-DIONE, Tetrahedron letters, 37(49), 1996, pp. 8861-8864
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
49
Year of publication
1996
Pages
8861 - 8864
Database
ISI
SICI code
0040-4039(1996)37:49<8861:PTA1D>2.0.ZU;2-8
Abstract
The cycloaddition of hex-3-yn-2,5-dione onto a pi-CS2 Iron complex 3 a nd on 3-thioxo-1,2-dithioles affords diacetylated intermediates which can be readily converted into di or tetraacetylated derivatives of the 1,3-dithiole (5,6) and tetrathiafulvalene (2,8) series, some represen tative electrochemical and structural features of which being also pre sented. Copyright (C) 1996 Published by Elsevier Science Ltd.