Mr. Lee et al., AQUEOUS ALTERATION IN THE MATRIX OF THE VIGARANO (CV3) CARBONACEOUS CHONDRITE, Meteoritics & planetary science, 31(4), 1996, pp. 477-483
The matrix of Vigarano, a meteorite which belongs to the reduced subgr
oup of the CV3 chondrites, contains small amounts (<10%) of ferrihydri
te and smectite. These hydrous minerals occur together as fine fibrous
intergrowths between anhydrous silicate and oxide grains. Coarser cry
stals of ferrihydrite fill fractures that cut matrix minerals, and sme
ctite also lines narrow channels within olivine grains. These channels
may have formed by preferential alteration of olivines along (100)-pa
rallel defects. Formation of ferrihydrite and smectite in the matrix o
f Vigarano was the result of mild aqueous alteration in a low-temperat
ure (<150 degrees C), oxidising parent body environment. Partial equil
ibration of matrix olivines indicates that alteration was followed by
thermal metamorphism with a peak temperature of 400-500 degrees C. Min
eralogically similar alteration products, which also were formed by pa
rent body processes, have previously been described from the matrices
of four CV meteorites: Ball, Grosnaja, Kaba and Mokoia, all of which b
elong to the oxidised subgroup. This discovery of the products of oxid
ative aqueous alteration in Vigarano has important consequences for un
derstanding the chemical and thermal history of the CV class of meteor
ites.