CHIRAL DIENOLATE CHEMISTRY IN REMOTE ASYMMETRIC INDUCTION - THE ASYMMETRIC ALDOL OXY-COPE STRATEGY FOR ASYMMETRIC-SYNTHESIS OF GAMMA,DELTA-DICHIRAL ALPHA,BETA-UNSATURATED ACID-DERIVATIVES/

Authors
TOMOOKA K NAGASAWA A WEI SY NAKAI T
Citation
K. Tomooka et al., CHIRAL DIENOLATE CHEMISTRY IN REMOTE ASYMMETRIC INDUCTION - THE ASYMMETRIC ALDOL OXY-COPE STRATEGY FOR ASYMMETRIC-SYNTHESIS OF GAMMA,DELTA-DICHIRAL ALPHA,BETA-UNSATURATED ACID-DERIVATIVES/, Tetrahedron letters, 37(49), 1996, pp. 8899-8900
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
49
Year of publication
1996
Pages
8899 - 8900
Database
ISI
SICI code
0040-4039(1996)37:49<8899:CDCIRA>2.0.ZU;2-I
Abstract
The asymmetric aldol reaction of the boron dienolate derived from chir al alpha,beta- or beta, gamma-unsaturated imide followed by the siloxy -Cope rearrangement is shown to provide the gamma,delta-anti- or -syn -alpha,beta-unsaturated imide as the main product. Copyright (C) 1996 Elsevier Science Ltd