ABSOLUTE INTENSITIES IN THE NU(2) FUNDAMENTAL OF N2O AT 17-MU-M

Citation
Jwc. Johns et al., ABSOLUTE INTENSITIES IN THE NU(2) FUNDAMENTAL OF N2O AT 17-MU-M, Journal of molecular spectroscopy, 177(2), 1996, pp. 203-210
Citations number
31
Categorie Soggetti
Spectroscopy,"Physics, Atomic, Molecular & Chemical
ISSN journal
00222852
Volume
177
Issue
2
Year of publication
1996
Pages
203 - 210
Database
ISI
SICI code
0022-2852(1996)177:2<203:AIITNF>2.0.ZU;2-0
Abstract
Absolute intensity measurements have been made in the nu(2) fundamenta l band of nitrous oxide (N2O). The experiments were carried out indepe ndently in two laboratories and despite the fact that the two Fourier transform instruments are very different and required different data r eduction techniques the results agree within the estimated experimenta l errors. The square of the transition dipole is found to be 4.7538(58 ) x 10(-3) D-2 and in addition there is a large Linear Herman-Wallis f actor which gives rise to an R branch that is significantly stronger t han the P branch.