METHOXY-PALLADATION OF ALLYLAMINES - A FACILE SYNTHESIS OF CHIRAL CYCLOPALLADATED COMPOUNDS - X-RAY CRYSTAL-STRUCTURE OF TRANS[PD(CH2CH(OME)CH(ME)NME(2))(CL)(PY)]

Authors
DUPONT J HALFEN RAP SCHENATO R BERGER A HORNER M BORTOLUZZI A MAICHLEMOSSMER C
Citation
J. Dupont et al., METHOXY-PALLADATION OF ALLYLAMINES - A FACILE SYNTHESIS OF CHIRAL CYCLOPALLADATED COMPOUNDS - X-RAY CRYSTAL-STRUCTURE OF TRANS[PD(CH2CH(OME)CH(ME)NME(2))(CL)(PY)], Polyhedron, 15(20), 1996, pp. 3465-3468
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
15
Issue
20
Year of publication
1996
Pages
3465 - 3468
Database
ISI
SICI code
0277-5387(1996)15:20<3465:MOA-AF>2.0.ZU;2-J
Abstract
The reaction of racemic N,N-dimethylamino-3-but-1-ene (1) and N,N-dime thylamino-1-cyclohex-2-ene (2) with Li2PdCl4 in methanol at 0 degrees C yielded [Pd(CH2CH(OMe)CH(Me)NMe(2))(mu-Cl)](2) (4) and [Pd(CHCH(OMe) CHNMe(2)(CH2)(3))(mu-Cl)](2) (6), respectively, as single isomers. On the other hand, only the deallylation product trans-PdCl2[NH-(R,R)-(Me CHPh)(2)](2) (8) was isolated from the reaction of (R,R)-alpha,alpha-d imethyldibenzylallylamine with palladium(II) salts. Copyright (C) 1996 Elsevier Science Ltd