PHOSPHAZENES WITH (2-PYRIDYLMETHYLAMINO) GROUPS .1. SYNTHESES AND CRYSTAL-STRUCTURES OF TAPHENOXY(2-PYRIDYLMETHYLAMINO)CYCLOTRIPHOSPHAZENE AND ITS COPPER(II) NITRATE, PLATINUM(II) CHLORIDE, AND COBALT(II) NITRATE COMPLEXES

Authors
DIEFENBACH U KRETSCHMANN M STROMBURG B
Citation
U. Diefenbach et al., PHOSPHAZENES WITH (2-PYRIDYLMETHYLAMINO) GROUPS .1. SYNTHESES AND CRYSTAL-STRUCTURES OF TAPHENOXY(2-PYRIDYLMETHYLAMINO)CYCLOTRIPHOSPHAZENE AND ITS COPPER(II) NITRATE, PLATINUM(II) CHLORIDE, AND COBALT(II) NITRATE COMPLEXES, Chemische Berichte, 129(12), 1996, pp. 1573-1578
Citations number
36
Categorie Soggetti
Chemistry
Journal title
Chemische Berichte → ACNP
ISSN journal
00092940
Volume
129
Issue
12
Year of publication
1996
Pages
1573 - 1578
Database
ISI
SICI code
0009-2940(1996)129:12<1573:PW(G.S>2.0.ZU;2-5
Abstract
The reaction of the (2-pyridylmethylamino)-substituted cyclotriphospha zene N3P3(OC6H5)(5)(NHCH2(C5H4N)-2) (1) with copper(II) nitrate, plati num(II) chloride, and cobalt(II) nitrate yields the stable complexes [ Cu(NO3)(2) .(1)(2)] (1a), [PtCl2 .(1)] (1b), [Co(NO3)(2) .(1)] (1c). T he X-ray crystallographic studies of these metal complexes revealed th e different coordination behavior of the multifunctional ligand.