SYNTHESIS AND NMR-SPECTRA OF THE HYDROXYUNDECAHYDRO-CLOSO-DODECABORATE [B12H11OH](2-) AND ITS ACYLATED DERIVATIVES

Authors
SEMIOSHKIN AA PETROVSKII PV SIVAEV IB BALANDINA EG BREGADZE VI
Citation
Aa. Semioshkin et al., SYNTHESIS AND NMR-SPECTRA OF THE HYDROXYUNDECAHYDRO-CLOSO-DODECABORATE [B12H11OH](2-) AND ITS ACYLATED DERIVATIVES, Russian chemical bulletin, 45(3), 1996, pp. 683-686
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
45
Issue
3
Year of publication
1996
Pages
683 - 686
Database
ISI
SICI code
1066-5285(1996)45:3<683:SANOTH>2.0.ZU;2-N
Abstract
Tetrabutylammonium hydroxyundecahydro-closo-dodecaborate was obtained in high yield via [B(12)H(11)NMP](-)(NMP = N-methylpyrrolidone) by the modified method. [B12H11OH](2-) is easily acylated by aromatic acyl c hlorides to give novel compounds [B12H11OCOAr](2-) in high yields. All the compounds were characterized by standard and special NMR methods.