PHOTOLYSIS OF TRIPHENYL PHOSPHATE IN AQUEOUS-METHANOL

Citation
Y. Okamoto et al., PHOTOLYSIS OF TRIPHENYL PHOSPHATE IN AQUEOUS-METHANOL, Heteroatom chemistry, 7(4), 1996, pp. 257-261
Citations number
11
Categorie Soggetti
Chemistry
Journal title
ISSN journal
10427163
Volume
7
Issue
4
Year of publication
1996
Pages
257 - 261
Database
ISI
SICI code
1042-7163(1996)7:4<257:POTPIA>2.0.ZU;2-T
Abstract
Upon UV irradiation in methanol, triphenylphosphate (1a) gave biphenyl yl phenyl phosphate (2a) as the main product, whereas the addition of water to the solution caused an increase of the yield of biphenyl (3a) . These products were formed through a singlet excited state and an in tramolecular excimer, respectively. (C) 1996 John Wiley & Sons, Inc.