Lv. Gasparov et al., ELECTRONIC RAMAN-SCATTERING OF TL-2201 AND TL-2223 AND THE SYMMETRY OF THE ENERGY-GAP, Physica. B, Condensed matter, 224(1-4), 1996, pp. 484-489
The high temperature superconductors Tl2Ba2CuO6+delta (Tl-2201) and Tl
2Ba2Ca2Cu3O10 (Tl-2223) with one and three CuO2 planes were investigat
ed by Raman scattering in order to see whether the electronic Raman sc
attering cross-section depends on the number of CuO2 planes, i.e. shee
ts of the Fermi surface, We present measurements of polarized Raman sp
ectra in different scattering geometries on two single crystals of Tl-
2201 (T-c = 90 K, 80 K), and one single crystal of Tl-2223 (T-c = 118
K), for temperatures below and above T-c. In B-1g-symmetry the peak in
the electronic Raman scattering is found at 460 cm(-1)(T-c = 90 K), o
r 430 cm(-1) (T-c = 80 K) for Tl-2201 and at 610 cm(-1) for Tl-2223. T
his corresponds to 2 Delta/k(B)T(c) = 7.4 +/- 0.4 for both compounds.
The A(1g)- and B-2g-symmetry components show smaller values for the pe
ak position and a decrease linear in omega of the scattering intensity
towards lower frequencies. The B-1g-component shows a decrease cubic
in omega of the scattering intensity towards lower frequencies. The sp
ectral features of Tl-2201 and Tl-2223 are found to be independent of
the number of CuO2-planes, i.e. of specific details of the Fermi surfa
ce. These observations are similar to the measurements on over- and un
derdoped Bi2Sr2CaCu2O8+delta single crystals. They are consistent with
a d(x1-y1)-wave pairing mechanism, based on the theoretical model of
Devereaux and Einzel.