A. Bogaerts et al., 2-DIMENSIONAL MODEL OF A DIRECT-CURRENT GLOW-DISCHARGE - DESCRIPTION OF THE ELECTRONS, ARGON IONS, AND FAST ARGON ATOMS, Analytical chemistry, 68(14), 1996, pp. 2296-2303
To improve the analytical results of techniques that use the glow disc
harge as spectroscopic source, a good insight into the glow discharge
is desirable, This can be obtained by mathematical modeling. In this w
ork, a two-dimensional model is developed to describe the electrons, a
rgon ions, and fast argon atoms in a direct current glow discharge in
argon, The model consists of a Monte Carlo model for the fast electron
s, a Monte Carlo model for the argon ions and fast argon atoms in the
cathode dark space, and a fluid model for the argon ions and slow elec
trons. Results in two dimensions are presented for a standard flat cel
l of the VG 9000 glow discharge mass spectrometer (VG Elemental, Fison
s); they include the densities, mean energies, and collision rates of
the plasma species, the potential distribution, and the axial and radi
al electric fields.