CARBONYL[TRIS(2-METHOXYPHENYL)PHOSPHINE-P]CHROMIUM AND ITS MOLYBDENUMANALOG

Authors
BINSHAWKATALY O SAMINATHAN T MUNISWARAN K FUN HK SIVAKUMAR K
Citation
O. Binshawkataly et al., CARBONYL[TRIS(2-METHOXYPHENYL)PHOSPHINE-P]CHROMIUM AND ITS MOLYBDENUMANALOG, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 1352-1355
Citations number
7
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
6
Pages
1352 - 1355
Database
ISI
SICI code
0108-2701(1996)52:<1352:CAIM>2.0.ZU;2-N
Abstract
In the title compounds, [Cr(C21H21O3P)(CO)(5)] and [Mo(C-21 H21O3P)(CO )(5)], the M-C bend lengths for the cis-carbonyl ligands (with respect to the phosphine) are longer than that observed for the trans-carbony l group. The chromium compound has short intermolecular O ... O contac ts, The two crystal structures are not isomorphous and crystallize in triclinic and monoclinic systems, respectively.