YCLOPENTADIENYL)(TRIMETHYLSILYLMETHYL)TUNGSTEN(VI)

Authors
LEGZDINS P RETTIG SJ SAYERS SF
Citation
P. Legzdins et al., YCLOPENTADIENYL)(TRIMETHYLSILYLMETHYL)TUNGSTEN(VI), Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 1355-1357
Citations number
7
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
6
Pages
1355 - 1357
Database
ISI
SICI code
0108-2701(1996)52:<1355:Y>2.0.ZU;2-P
Abstract
(eta(5)-C(5)Me(5))WO2(CH(2)SiMe(3)), which has crystallographic mirror symmetry, exhibits the three-legged piano stool geometry typical for complexes of this type. The pentamethylcyclopentadienyl ligand is asym metrically bound to the metal atom [W-C=2.321 (8)-2.477 (4) Angstrom]. The W=O and W-C(alkyl) distances are 1.717 (4) and 2.128 (8) Angstrom , respectively.