THE FIRST MU(4)-SE SPIRO-TYPE FE4SE3 CLUSTER - [(MU-4-CH3-C6H4SE)FE-2(CO)(6)](2)(MU(4)-SE)

Authors
SONG LC HU QM YAN CG WANG RJ MAK TCW
Citation
Lc. Song et al., THE FIRST MU(4)-SE SPIRO-TYPE FE4SE3 CLUSTER - [(MU-4-CH3-C6H4SE)FE-2(CO)(6)](2)(MU(4)-SE), Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 1357-1359
Citations number
6
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
6
Pages
1357 - 1359
Database
ISI
SICI code
0108-2701(1996)52:<1357:TFMSFC>2.0.ZU;2-O
Abstract
In the molecule of the title cluster compound, mu(4)-selenido-bis [mu- (4-tolylselenido)-hexacarbonyldiiron], two identical (mu-4-CH3C6H4Se)F e-2(CO)(6) moieties are joined by a spiro-type four-coordinate Se atom , mu(4)-Se. The four Se-Fe bond lengths around the central Se atom are 2.353 (3), 2,353 (3), 2.347 (3) and 2.358 (3) Angstrom. The average ( 2.353 Angstrom) is shorter than that (2.392 Angstrom) of Se-Fe bond le ngths formed between Fe atoms and the 4-tolylselenido ligands. In each diiron subcluster core, the 4-tolylselenido ligand is bridged between two Fe atoms.