ETHYLPHOSPHONO-2'-O-TERT-BUTYLDIMETHYLSILYLURIDINE

Authors
MCELDOON WL SWENSON DC WIEMER DF
Citation
Wl. Mceldoon et al., ETHYLPHOSPHONO-2'-O-TERT-BUTYLDIMETHYLSILYLURIDINE, Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 1552-1554
Citations number
9
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
6
Pages
1552 - 1554
Database
ISI
SICI code
0108-2701(1996)52:<1552:E>2.0.ZU;2-E
Abstract
3'-Hydroxy-3'-diethylphosphononucleosides readily undergo radical deox ygenation under modified Barton conditions to give two diastereomers o f the parent diethyl phosphonate. However, the stereochemistry of the diastereomers is difficult to establish by spectral means. When the ma jor product of one such reaction was obtained in crystalline form, a s ingle crystal diffraction analysis was conducted on that diastereomer, the title compound, C26H39N2O9PSi.