A KEY INTERMEDIATE IN THE SYNTHESIS OF (-HERNANDULCIN())

Authors
ZUKERMANSCHPECTOR J CARACELLI I DEOLIVEIRA SM DEMEDEIROS EF BROCKSOM T
Citation
J. Zukermanschpector et al., A KEY INTERMEDIATE IN THE SYNTHESIS OF (-HERNANDULCIN()), Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 1579-1581
Citations number
7
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
6
Pages
1579 - 1581
Database
ISI
SICI code
0108-2701(1996)52:<1579:AKIITS>2.0.ZU;2-R
Abstract
l-5-[(1'R,2'R,4'R)-2'-acetoxy-4'-methylcyclohexyl] -Delta(2)-isoxazoli ne (C14H23NO3) is a key intermediate in the reaction pathway aiming at the synthesis of (+)-hernandulcin. The five-membered heterocycle ring is in a twist conformation and the cyclohexane ring is in a chair con formation, The molecular packing involves C-H ... O intermolecular con tacts.