Gs. Iannacchione et al., DEUTERIUM NMR AND MORPHOLOGY STUDY OF POLYMER-DISPERSED LIQUID-CRYSTAL BRAGG GRATINGS, Europhysics letters, 36(6), 1996, pp. 425-430
The orientational order in polymer-dispersed liquid crystals on hologr
aphically written volume Bragg gratings is studied using deuterium NMR
. Unique spectral patterns indicate that a homeotropic liquid-crystal
director configuration at the polymer interface is retained despite th
e small pore size (< 100nm). This structure coexists with liquid cryst
als in trapped defect structures of dimension comparable to the pore s
ize.