Js. Lord et al., A NUCLEAR-MAGNETIC-RESONANCE INVESTIGATION OF THE FERROMAGNETIC PHASEOF CEPDSB AS A FUNCTION OF TEMPERATURE AND PRESSURE, Journal of physics. Condensed matter, 8(29), 1996, pp. 5475-5482
The ferromagnetic state of CePdSb below 17 K has been confirmed by zer
o-field Sb NMR. The effective field (B-eff) at the Sb nucleus at low t
emperature is +2.78 T and the quadrupole interaction (v(q)) is 3.8 (2.
3) MHz for Sb-121 (Sb-123). The NMR spectra do nor reflect reported ma
gnetic behaviour at 6 K. The transition at this temperature is therefo
re thought to be due to a second phase. The value of partial derivativ
e ln B-eff/partial derivative P is +6.3 Mbar(-1), which is similar to
that of partial derivative ln T-c/partial derivative P, +14 Mbar(-1).
The value of partial derivative ln v(q)/partial derivative P is -28 Mb
ar(-1), which is estimated to be approximate to -28 times the value ex
pected for an isotropic elastic solid. The elastic properties of CePdS
b are therefore predicted to be extremely anisotropic. The temperature
dependence of B-eff was measured from 1.4-15 K but measurements are r
equired to lower temperatures before it can be decided whether a 4.5 K
gap exists in the spin-wave spectrum, as postulated from heat capacit
y measurements.