MOLYBDENUM(VI) AND TUNGSTEN(VI) CATALYSIS OF PERBORATE OXIDATION OF ANILINE

Authors
KARUNAKARAN C PALANISAMY PN
Citation
C. Karunakaran et Pn. Palanisamy, MOLYBDENUM(VI) AND TUNGSTEN(VI) CATALYSIS OF PERBORATE OXIDATION OF ANILINE, Polish Journal of Chemistry, 70(12), 1996, pp. 1573-1578
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Polish Journal of Chemistry → ACNP
ISSN journal
01375083
Volume
70
Issue
12
Year of publication
1996
Pages
1573 - 1578
Database
ISI
SICI code
0137-5083(1996)70:12<1573:MATCOP>2.0.ZU;2-X
Abstract
Molybdenum(VI) and tungsten(VI) catalyze perborate oxidation of anilin e to azobenzene in aqueous acetic acid and tile catalyzed oxidations a re zero, First and second order in the oxidant, catalysts and substrat e, respectively. Tile reactive species of perborate is H2O2 and the me chanism of catalysis is discussed.