N. Wen et al., THE GENESIS OF CU-BEARING QUARTZ VEINS BY METAMORPHIC REMOBILIZATION FROM STRATIFORM RED-BED DEPOSITS, SW COUNTY-CORK, IRELAND, Mineralogy and petrology, 57(1-2), 1996, pp. 73-89
Polymetallic major veins of the West Carbery district (County Cork) ar
e compared with the nearby stratiform-disseminated copper mineralizati
on in metasedimentary rocks, containing minor veins (metamorphic quart
z veins and veinlets). These stratiform deposits are hosted by non-mar
ine Devonian sediments (Old Red Sandstone), metamorphosed in the Hercy
nian orogeny. In sulphides from the stratiform deposits and minor vein
s, isotopic compositions of sulphur (delta(34)S) range from -21.00 to
+5.14 parts per thousand, consistent with the vein sulphide being remo
bilized stratiform-disseminated sulphide, and the latter being of diag
enetic bacteriogenic origin. Sulphate (barite), found in veins separat
e from the sulphides, has delta(34)S + 12.3 to 15.7 parts per thousand
, consistent with groundwater origin. In minor-vein quartz, fluid incl
usions have homogenization temperatures consistent with trapping under
the estimated peak-metamorphic conditions (300-400 degrees C, 1-3 kba
r). In the major veins, sulphide delta(34)S (-15.8 to -4.2 parts per t
housand,) suggest remobilization of diagenetic sulphide. Oxygen and hy
drogen isotopes suggest deposition from metamorphic fluids (calculated
delta(18)O(H2O), approximately +8 to +13 parts per thousand, measured
range of delta D -52.2 to -27.3 parts per thousand). Immiscible CO2-b
earing fluids were trapped in the temperature range 280-350 degrees C
with fluid pressure < ca. 600 bar. The inferred pressure-temperature h
istory is attributed to late-metamorphic uplift, with fluid pressures
falling below lithostatic. The sulphide-bearing veins are interpreted
as a small-scale example of redistribution of mineral deposits by meta
morphic fluids.