MECHANISM OF FORMATION OF PEROXOCARBONATES RHOOC(O)O(CL)(P)(3) AND THEIR REACTIVITY AS OXYGEN-TRANSFER AGENTS MIMICKING MONOOXYGENASES - THE FIRST EVIDENCE OF CO2 INSERTION INTO THE O-O BOND OF RH(ETA(2)-O-2) COMPLEXES

Authors
ARESTA M TOMMASI I QUARANTA E FRAGALE C MASCETTI J TRANQUILLE M GALAN F FOUASSIER M
Citation
M. Aresta et al., MECHANISM OF FORMATION OF PEROXOCARBONATES RHOOC(O)O(CL)(P)(3) AND THEIR REACTIVITY AS OXYGEN-TRANSFER AGENTS MIMICKING MONOOXYGENASES - THE FIRST EVIDENCE OF CO2 INSERTION INTO THE O-O BOND OF RH(ETA(2)-O-2) COMPLEXES, Inorganic chemistry, 35(14), 1996, pp. 4254-4260
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
35
Issue
14
Year of publication
1996
Pages
4254 - 4260
Database
ISI
SICI code
0020-1669(1996)35:14<4254:MOFOPR>2.0.ZU;2-U
Abstract
Extended labeling experiments have shown that formation of rhodium per oxocarbonate from CO2 and [RhCl(eta(2)-O-2)(P)(3)] (P is PEt(2)Ph or P EtPh(2)) proceeds through O-O bond cleavage and CO2 insertion. O-trans fer to ancillary phosphine ligand to give R(3)P=O selectively (>85%) i nvolves the Ph-linked O atom of the peroxo group of RhCl(CO4)(P)(3).