SYNTHESIS, CRYSTAL-STRUCTURE AND CHARACTERIZATION OF THE HETEROMETALLIC TETRANUCLEAR BUTTERFLY CLUSTER [RU3IRH2(CO)(12)CL]

Authors
HARKONEN AU AHLGREN M PAKKANEN TA PURSIAINEN J
Citation
Au. Harkonen et al., SYNTHESIS, CRYSTAL-STRUCTURE AND CHARACTERIZATION OF THE HETEROMETALLIC TETRANUCLEAR BUTTERFLY CLUSTER [RU3IRH2(CO)(12)CL], Journal of organometallic chemistry, 519(1-2), 1996, pp. 205-208
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
519
Issue
1-2
Year of publication
1996
Pages
205 - 208
Database
ISI
SICI code
0022-328X(1996)519:1-2<205:SCACOT>2.0.ZU;2-N
Abstract
A new iridium-ruthenium mixed-metal cluster [Ru3IrH2(CO)(12)Cl] has be en synthesized and its structure has been determined by single-crystal X-ray diffraction. [Ru3IrH2(CO)(12)Cl] shows a butterfly arrangement of metal atoms; with three terminal carbonyls on each metal atom and w ith the hydride ligands at Ru-Ru edges.