THE CHARACTERIZATION AND TEST REACTION OF CYCLOHEXANOL OVER ZEOLITES SILICO-ALUMINOPHOSPHATES AND CHROMITE CATALYSTS

Citation
Kvvsbsr. Murthy et al., THE CHARACTERIZATION AND TEST REACTION OF CYCLOHEXANOL OVER ZEOLITES SILICO-ALUMINOPHOSPHATES AND CHROMITE CATALYSTS, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 35(8), 1996, pp. 649-655
Citations number
10
Categorie Soggetti
Chemistry
ISSN journal
03764710
Volume
35
Issue
8
Year of publication
1996
Pages
649 - 655
Database
ISI
SICI code
0376-4710(1996)35:8<649:TCATRO>2.0.ZU;2-E
Abstract
The reaction of cyclohexanol has been carried out over HZSM-5, HY, var ious silicoaluminophosphate (SAPO), MSAPO and chromite catalysts activ e in cyclization reactions. The reaction was caried out in the tempera ture range of 180 degrees-350 degrees C and 0.5 h(-1) weight hourly sp ace velocity. All the catalysts show high activity. All SAPO catalysts show the presence of acidic active centres. The chromite catalysts sh ow the presence of acidic and strong basic active centres. The SAPO, M SAPO catalysts are characterized by X-ray diffraction, IR, ESR and XPS techniques.