SYNTHESIS, CHARACTERIZATION AND ELECTROCHEMISTRY OF UNSYMMETRICAL MACROCYCLIC COBALT(II) COMPLEXES DERIVED FROM BIS(BENZIL)ETHYLENEDIIMINE

Authors
REDDY MR RAJU KM REDDY KH
Citation
Mr. Reddy et al., SYNTHESIS, CHARACTERIZATION AND ELECTROCHEMISTRY OF UNSYMMETRICAL MACROCYCLIC COBALT(II) COMPLEXES DERIVED FROM BIS(BENZIL)ETHYLENEDIIMINE, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 35(8), 1996, pp. 677-680
Citations number
22
Categorie Soggetti
Chemistry
Journal title
Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical → ACNP
ISSN journal
03764710
Volume
35
Issue
8
Year of publication
1996
Pages
677 - 680
Database
ISI
SICI code
0376-4710(1996)35:8<677:SCAEOU>2.0.ZU;2-1
Abstract
Macrocyclic cobalt(II) complexes with varying ring sizes (12-14 member ed) have been synthesized by using template method with bis(benzil)eth ylenediamine precursor. These complexes have been characterized by ele mental analyses, conductance, IR and electronic spectra. The spectral data suggest octahedral geometry for all the complexes. Various ligand field parameters have been calculated. The CV results suggest that th e cobalt complexes derived from aromatic diamines are reduced at more negative potentials.