B. Mudford et I. Lerche, DISENTANGLEMENT OF HYDROGEN INDEX AND S1 TOTAL ORGANIC-CARBON VARIATIONS WITH DEPTH/, Energy & fuels, 10(4), 1996, pp. 905-914
Many workers, especially in coal studies, have suggested that changes
which occur during pyrolysis studies could lead to mobile components b
eing retained within the macromolecular network, rather than being ins
tantaneously released. This process has the potential to cloud the res
ults from ROCK EVAL pyrolysis. We present a procedure that can be used
to disentangle the effects of delayed emission of mobile components d
uring ROCK EVAL pyrolysis. This procedure is illustrated using four we
lls from East Kalimantan, Indonesia, which have hydrogen index (HI) vs
depth curves that increase with depth, contrary to conventional expec
tations. The disentanglement procedure developed in this paper is used
to show that delayed emission may be an explanation for the anomalous
HI vs depth behavior in these wells. Possible delayed emission of S1
products may adulterate the S1 and S2 signals, requiring that this pos
sibility be considered during ROCK EVAL pyrolysis data analysis.