ELECTRICAL AND INTERFACIAL PROPERTIES OF A LI3FE2(PO4)(3) SINGLE-CRYSTAL WITH SILVER ELECTRODES

Authors
IVANOVSCHITZ AK SCHOONMAN J
Citation
Ak. Ivanovschitz et J. Schoonman, ELECTRICAL AND INTERFACIAL PROPERTIES OF A LI3FE2(PO4)(3) SINGLE-CRYSTAL WITH SILVER ELECTRODES, Solid state ionics, 91(1-2), 1996, pp. 93-99
Citations number
23
Categorie Soggetti
Physics, Condensed Matter","Chemistry Physical
Journal title
Solid state ionics → ACNP
ISSN journal
01672738
Volume
91
Issue
1-2
Year of publication
1996
Pages
93 - 99
Database
ISI
SICI code
0167-2738(1996)91:1-2<93:EAIPOA>2.0.ZU;2-Y
Abstract
Electrical conductivity and thermal properties of Li3Fe2(PO4)(3) singl e crystals have been studied over a wide temperature range. The phase transformation detected at 483 K by DSC is accompanied by an anomaly o f the conductivity for crystals oriented along the b-axis. The transit ion to the high-temperature fast ionic phase is observed at about 588 K for crystals oriented along [101] and [10 (1) over bar] directions. The highest conductivity is observed for measurements perpendicular to the b-axis.