A. Brau et al., THERMISTOR EFFECT AND CURRENT-INDUCED TRANSITION IN COPPER-TETRACYANOQUINODIMETHANE COMPOSITES, Solid state ionics, 91(1-2), 1996, pp. 137-143
We present a study of thermistor effect and current induced transition
in compacted mixed powders of copper and tetracyanoquinodimethane (TC
NQ). We confirm first, a previous estimate of the yield of charge tran
sfer reaction between the components. Then, thermistance (current-volt
age) characteristics of these composites are investigated in connectio
n with the degree of ionicity of TCNQ as deduced from infrared absorpt
ion spectroscopy.