SYNTHESIS OF NEW HYDROPHILIC PHOSPHINES - INFLUENCE OF THE SULFONATE COUNTERION ON A CARBON-CARBON COUPLING REACTION

Authors
LAVENOT L ROUCOUX A PATIN H
Citation
L. Lavenot et al., SYNTHESIS OF NEW HYDROPHILIC PHOSPHINES - INFLUENCE OF THE SULFONATE COUNTERION ON A CARBON-CARBON COUPLING REACTION, Comptes rendus de l'Academie des sciences. Serie II. Mecanique, physique, chimie, astronomie, 323(1), 1996, pp. 59-65
Citations number
9
Categorie Soggetti
Multidisciplinary Sciences
Journal title
Comptes rendus de l'Academie des sciences. Serie II. Mecanique, physique, chimie, astronomie → ACNP
ISSN journal
12518069
Volume
323
Issue
1
Year of publication
1996
Pages
59 - 65
Database
ISI
SICI code
1251-8069(1996)323:1<59:SONHP->2.0.ZU;2-U
Abstract
We describe the synthesis of new alkyldiphenylphosphines bearing one s ulfonate group associated with various cations: sodium or tetraalkylam monium. The surface tensions of the phosphines were measured cationic and neutral rhodium (I) coordination compounds were also characterized Condensation between myrcene and methylacetylacetate was the model re action chosen in order to evaluate the influence on the conversion rat e of the counter-ion lipophillicity.