The nature of electronic interaction between noble metal and semicondu
cting oxide was investigated for Pd-loaded SnO2 sensor elements. It wa
s shown that SnO2 grains contacting to PdO were strongly depleted of e
lectrons in air. This electronic interaction disappears on exposure no
t only to H-2-containing air but also to He (inert gas). On the basis
of these results, it was suggested that the adsorbed oxygen formed at
the PdO-SnO2 interface is responsible for the electronic interaction.