Ra. Gordon et al., ELECTRIC AND MAGNETIC-BEHAVIOR OF CE(8)PD(24)M COMPOUNDS WITH M=(GA,IN,SN,PB,SB AND BI), Physica. B, Condensed matter, 225(1-2), 1996, pp. 23-32
We have prepared and examined the resistivity and magnetic susceptibil
ity of a series of ternary compounds with composition Ce(8)Pd(24)M, wh
ere M is one of Ga, In, Sn, Sb, Pb or Bi, and the related composition
La8Pd24In. All members of this series are cubic with effective cerium
moments consistent with trivalent cerium. The lanthanum compound behav
es as a simple metal in resistivity and has a small, negative suscepti
bility at 295 K. All the cerium compounds but the gallide exhibit anti
ferromagnetic ordering below 10 K. Metallic behaviour is observed for
all. The properties of the stannide, plumbide, antimonide and bismuthi
de reflect some weak interactions with crystal-field-split cerium stat
es above 30 K and changes in slope at low temperature coincident with
the second-order antiferromagnetic phase transitions. Resistivities fo
r the gallide and indide display broad features near 15 and 50 K, resp
ectively, suggesting that a strong Kondo interaction is present in the
se materials.