INFRARED-SPECTRUM OF THE BIS-(1,10-PHENANTHROLINE) CU(I) AND CU(II) PERCHLORATE COMPLEXES

Authors
CAMPOSVALLETTE MM CLAVIJO RE MENDIZABAL F ZAMUDIO W BARAONA R DIAZ G
Citation
Mm. Camposvallette et al., INFRARED-SPECTRUM OF THE BIS-(1,10-PHENANTHROLINE) CU(I) AND CU(II) PERCHLORATE COMPLEXES, Vibrational spectroscopy, 12(1), 1996, pp. 37-44
Citations number
38
Categorie Soggetti
Spectroscopy,"Chemistry Analytical","Chemistry Physical
Journal title
Vibrational spectroscopy → ACNP
ISSN journal
09242031
Volume
12
Issue
1
Year of publication
1996
Pages
37 - 44
Database
ISI
SICI code
0924-2031(1996)12:1<37:IOTBCA>2.0.ZU;2-U
Abstract
FT-IR spectra of the title compounds and derivatives were measured in the range 4000-120 cm(-1). A complete cm experimental spectral assignm ent has been performed. A simplified normal coordinate treatment orien tates some assignment of frequencies in the low energy region. Bands a t ca. 420 and 300 cm(-1) are ascribed to the nu Cu-N modes. A stabilit y order of the Cu(I) complexes is proposed on the basis of their Cu-N frequency values.