Instruments based on ultrasonic spectrometry are becoming increasingly
popular for determining the droplet size distribution of emulsions. T
hey have major advantages over alternative technologies because they a
re capable of analyzing emulsions which are concentrated and optically
opaque, without disturbing the sample. This article reviews the physi
cal principles of ultrasonic particle sizing, the experimental methods
commonly used to make ultrasonic measurements, and the mathematical e
quations used to convert ultrasonic measurements to droplet size distr
ibutions. Ultrasonic spectrometry is compared to other particle-sizing
techniques so that colloid scientists can decide whether it is suitab
le for their particular application.