MU-BROMO-MU-PHOSPHIDO-BIS(TETRACARBONYLMANGANESE) AND DI-MU-PHOSPHIDO-BIS(TETRACARBONYLMANGANESE) - COCRYSTALLIZATION AND DISORDER

Authors
FLORKE U
Citation
U. Florke, MU-BROMO-MU-PHOSPHIDO-BIS(TETRACARBONYLMANGANESE) AND DI-MU-PHOSPHIDO-BIS(TETRACARBONYLMANGANESE) - COCRYSTALLIZATION AND DISORDER, Zeitschrift fur Kristallographie, 211(12), 1996, pp. 908-910
Citations number
8
Categorie Soggetti
Crystallography
Journal title
Zeitschrift fur Kristallographie → ACNP
ISSN journal
00442968
Volume
211
Issue
12
Year of publication
1996
Pages
908 - 910
Database
ISI
SICI code
0044-2968(1996)211:12<908:MAD>2.0.ZU;2-N
Abstract
(mu-Br)(mu-PH2)Mn-2(CO8) (I) and (mu-PH2)(2) . Mn-2(CO8) (II) co-cryst allize in space group P2(1)/c with a = 9.467(2) Angstrom, b = 12.181(2 ) Angstrom, c = 13.086(3) Angstrom, beta = 109.98(2)degrees, V = 1418. 2(5) Angstrom(3). The Mn-2(CO)(8) part of both molecules occupies the same site, the positions of the bromo and phosphido bridges show posit ional disorder. Average bond lengths are Mn-Br 2.606(5) Angstrom and M n-P 2.321(8) Angstrom.