The effects of starch variety and amylose on the rheological property
of rice starch during heating were investigated with mechanical spectr
ometry. The results indicated that the storage modulus (G)' of Kaoshiu
ng Sen 7 (KSS7, indica) starch with sufficient concentration increased
dramatically at gelatinization temperature (T-G'). T-G' was close to
T phi = 1, the temperature for the starch granule to become close-pack
ed. Nevertheless, T-G' was slightly lower than T phi = 1 in the low st
arch concentration system, and slightly higher in the high concentrati
on system. The addition of amylose inhibited the swelling of the starc
h granule, and consequently, T-G' raised slightly. With the addition o
f amylose, the G' of the starch gel decreased during heating, but may
have reinforced the close-packed swollen granule matrix during the per
iod of aging process at 5 degrees C. The waxy rice starch (Taichung wa
xy 70, TCW70) with trace amylose content, showed much higher swelling
power than that of indica rice starch (KSS7). Paste was formed even at
high concentration. The rigidity of starch granular structure might b
e in proportion to its amylose content and in inverse proportion to th
e degree of granular swelling. Hence, the higher G' for KSS7 rice star
ch than that for TCW70 can be explained by its high inherent amylose c
ontent, which could enhance the rigidity of the starch granular struct
ure. Also, the high G' value for the system with the high starch conce
ntration could be attributed to the low swelling and the strong intera
ction among the granules. From these results, it was concluded that th
e major influencing factors on the rheological property of the starch
during heating were the granular structure and component, followed by
the amount of leached-out amylose in the process.