M. Pauli et al., A NEW FABRICATION METHOD FOR MULTICRYSTALLINE SILICON LAYERS ON GRAPHITE SUBSTRATES SUITED FOR LOW-COST THIN-FILM SOLAR-CELLS, Solar energy materials and solar cells, 41-2, 1996, pp. 119-126
A new method for the fabrication of a columnar, multicrystalline silic
on layer on a graphite substrate is presented. This method basically i
nvolves three process steps: (1) Deposition of a thin (3-5 mu m) silic
on layer, (2) zone melting recrystallization of this layer with a line
electron beam as the heat source to form a multicrystalline seed laye
r, and (3) thickening of the seed layer by high temperature, epitaxial
chemical vapour deposition (CVD) to a thickness of 20-40 mu m The rec
rystallization leads to (110)[112]-textured silicon seed layers if suf
ficiently high scan velocities are applied. The degree of deviation fr
om the ideal (110)[112]-texture increases with decreasing scan velocit
y. The doping level of the seed layer is found to be only weakly affec
ted by the zone melting recrystallization. The epitaxial layer grown o
n top of the seed layer exhibits a columnar grain structure.