AN EFFICIENT NEW PYRIMIDINE SYNTHESIS - A PATHWAY TO OCTUPOLES

Citation
S. Brandl et al., AN EFFICIENT NEW PYRIMIDINE SYNTHESIS - A PATHWAY TO OCTUPOLES, Journal fur praktische Chemie, Chemiker-Zeitung, 338(5), 1996, pp. 451-459
Citations number
37
Categorie Soggetti
Chemistry,"Chemistry Applied
ISSN journal
09411216
Volume
338
Issue
5
Year of publication
1996
Pages
451 - 459
Database
ISI
SICI code
0941-1216(1996)338:5<451:AENPS->2.0.ZU;2-D
Abstract
The condensation of N,N,N'-tris(trimethylsilyl)amidines (6, 11, 22) wi th vinamidinium salts (1, 7) in the presence of potassium fluoride is the method of choice for the synthesis of pyrimidines (8, 12, 20, 23). Octupoles comprising 1,3,5-benzene (8) and triphenylamine (12, 20) de rivatives can be prepared in high yields.