This paper reports a method for the spectrofluorimetric identification
of fourteen polycyclic aromatic hydrocarbons (PAHs) at the nanogram p
er mililitre level in pure samples. The total fluorescence spectrum is
scanned asynchronously to record the fluorescence intensity at 15 pre
set excitation-emission wavelength pairs. By calculating a match index
between the unknown sample and a library of standard samples, the fou
rteen PAHs can be correctly identified. The match index obtained was a
lways greater than 0.95.