CONVERSION OF TRIFLUOROMETHYL-SUBSTITUTED PI-VINYLCARBENEIRON TO DIFLUOROTRIMETHYLENEMETHANE COMPLEXES

Authors
FUJITA K WATANABE Y MITSUDO T
Citation
K. Fujita et al., CONVERSION OF TRIFLUOROMETHYL-SUBSTITUTED PI-VINYLCARBENEIRON TO DIFLUOROTRIMETHYLENEMETHANE COMPLEXES, Chemistry Letters, (7), 1996, pp. 513-514
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
7
Year of publication
1996
Pages
513 - 514
Database
ISI
SICI code
0366-7022(1996):7<513:COTPTD>2.0.ZU;2-7
Abstract
A trifluoromethyl-substituted pi-vinylcarbeneiron complex reacts with [KB(sec-Bu)(3)H] or phenyllithium to afford difluorinated trimethylene methane iron complexes. This is the first example of the conversion of a pi-vinylcarbeneiron complex to a trimethylenemethane complex.