ENHANCING EFFECT OF TITANIUM(II) FOR THE OXIDATION OF METHANE WITH O-2 BY AN EUCL3-ZN-CF3CO2H-CATALYTIC SYSTEM AT 40-DEGREES-C

Authors
YAMANAKA I SOMA M OTSUKA K
Citation
I. Yamanaka et al., ENHANCING EFFECT OF TITANIUM(II) FOR THE OXIDATION OF METHANE WITH O-2 BY AN EUCL3-ZN-CF3CO2H-CATALYTIC SYSTEM AT 40-DEGREES-C, Chemistry Letters, (7), 1996, pp. 565-566
Citations number
5
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
7
Year of publication
1996
Pages
565 - 566
Database
ISI
SICI code
0366-7022(1996):7<565:EEOTFT>2.0.ZU;2-E
Abstract
Bis(2,4,-pentanedionate)TiO and TiO2 enhanced markedly the activity of the EuCl3-Zn-0-CF3CO2H-catalytic system for the CH, oxidation to MeOH with O-2 at 40 degrees C. It is suggested that Ti(II) species generat ed from Ti(TV) by the reduction with Zn-0 and CF3CO2H is responsible f or this enhancement.